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    Electrochemical Impedance Spectroscopy (EIS) has
    become a standard technique in the electrochemists’
    toolbox providing detailed information over very wide
    time scales and amplitudes. Commercial instruments
    are available that can measure impedances from m?
    to T? and over frequencies from μHz to MHz.
    Most commonly, EIS is measured using a “single-sine”
    method where individual frequencies are measured
    sequentially. One disadvantage of single-sine EIS is
    the time it takes to acquire a full spectrum. A
    complete sine wave cycle takes ~17 min at 1 mHz
    and ~27 hrs for 10 μHz. This disadvantage can be
    overcome by measuring multiple frequencies at the
    same time (akin to Fourier transform spectroscopy
    techniques).
    This application note discusses the use of multiple sine
    wave excitation in EIS and its implementation in
    Gamry Instrument software. It does not cover the
    basics of EIS which are described in the application
    note ”Basics of Electrochemical Impedance
    Spectroscopy”
    (http://www.gamry。。com/App_Notes/Index.htm).

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